nitrobenzene to azoxybenzene
The large size of silica particles also improves the colloidal stability of the small Rh nanocrystals, benefiting the photocatalytic performance. If you are on a personal connection, like at home, you can run an anti-virus scan on your device to make sure it is not infected with malware. Please reconnect. Please check your email for instructions on resetting your password. Learn about our remote access options, Department of Chemistry, Temple University, 1901 North 13th Street, Philadelphia, Pennsylvania, 19122 USA. Verhoeven, Y.-K. Sun. To understand why azoxybenzene was the predominant product, we performed several kinetic experiments . As a service to our authors and readers, this journal provides supporting information supplied by the authors. Russian Journal of Physical Chemistry A 2015 , 89 (10) , 1772-1775. Selective catalytic hydrogenation of nitrobenzene to hydrazobenzene. Kinetics of the hydrogenation of a mixture of nitrobenzene and azoxybenzene on skeletal nickel in an aqueous solution of propan-2-ol.
Find more information on the Altmetric Attention Score and how the score is calculated. Gold nanoparticles stabilized by phosphine-decorated polymer immobilized ionic liquids (AuNP@PPh2-PIILP) is an extremely efficient multiproduct selective catalyst for the sodium borohydride-mediated reduction of nitrobenzene giving N-phenylhydroxylamine, azoxybenzene, or aniline as the sole product under mild conditions and a very low catalyst loading. Rapid and green reduction of aromatic/aliphatic nitro compounds to amines with NaBH4 and additive Ni2B in H2O. Parametric study of temperature distribution in plasmon-assisted photocatalysis. Lei Hu, Xueqin Cao, Liang Chen, Junwei Zheng, Jianmei Lu, Xuhui Sun, Hongwei Gu.
Your Mendeley pairing has expired. Working off-campus? Click hereto get an answer to your question ️ Nitrobenzene is reduced to azoxybenzene using : Find more information about Crossref citation counts. C. LeBlond, J. Wang, R.D. The photocatalytic performance is enhanced by loading the Rh nanocrystals on dielectric silica spheres with sizes of hundreds of nanometers, which exhibit strong surface scattering resonances to increase the light absorption power in the Rh nanocrystals. Xinyan Dai. If you are at an office or shared network, you can ask the network administrator to run a scan across the network looking for misconfigured or infected devices. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, orcid.org/http://orcid.org/0000-0001-6351-6977, I have read and accept the Wiley Online Library Terms and Conditions of Use. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. The full text of this article hosted at iucr.org is unavailable due to technical difficulties.
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Highly efficient synthesis of aromatic azos catalyzed by unsupported ultra-thin Pt nanowires. Any queries (other than missing content) should be directed to the corresponding author for the article. and you may need to create a new Wiley Online Library account.
The initial reaction rates for the hydrogenation of nitrobenzene (r 1), nitrosobenzene (r 2), and azoxybenzene (r 3) were determined to be 0.34, … Photocatalytic hydrogenation of azobenzene to hydrazobenzene on cadmium sulfide under visible light irradiation. Nguen Tkhi Tkhu Kha, O. V. Lefedova, A. Orella, A.L. In lieu of an abstract, this is the article's first page. Department of Chemistry, Temple University, 1901 North 13th Street, Philadelphia, Pennsylvania, 19122 USA. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Kinetics and pathways of selective hydrogenation of 1-(4-nitrobenzyl)-1,2,4-triazole.
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https://doi.org/10.1016/j.jcat.2018.12.008, https://doi.org/10.1016/j.jhazmat.2015.09.029, https://doi.org/10.1134/S0036024415100222, https://doi.org/10.1007/s13738-014-0585-5, https://doi.org/10.1134/S0036024413040195, https://doi.org/10.1007/978-3-7091-6172-2_1, https://doi.org/10.1016/S0167-2991(97)80911-1. This study highlights the promise of hot electrons in catalyzing hydrogenation reaction with improved kinetics and selectivity.
Forman, F.P. Jee Eun Hong, Yeonghun Jung, Youmie Park. A. Merkin, A. R. Latypova, Nguen Tkhi Tkhu Kha, O. V. Lefedova. Gortsema, T.R. Your IP: 184.108.40.206 12 publications. Highly Dispersed RuOOH Nanoparticles on Silica Spheres: An Efficient Photothermal Catalyst for Selective Aerobic Oxidation of Benzyl Alcohol. You have to login with your ACS ID befor you can login with your Mendeley account. The reaction rate and product selectivity of nitrobenzene reduction catalyzed on Rh nanocrystals of several nanometers in size are significantly improved under illumination of visible light.
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• Note: A. Features of the kinetics of 4-nitroaniline and azoxybenzene hydrogenation in 2-propanol aqueous solutions. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. In this work, an active and selective heterogeneous catalyst for the oxidatio Qiuwen Liu, Yan Xu, Xiaoqing Qiu, Caijin Huang, Min Liu. the Altmetric Attention Score and how the score is calculated. Larsen, C.J. Completing the CAPTCHA proves you are a human and gives you temporary access to the web property. Use the link below to share a full-text version of this article with your friends and colleagues. Selective Transfer Coupling of Nitrobenzene to Azoxybenzene on Rh Nanoparticle Catalyst Promoted by Photoexcited Hot Electrons. Another way to prevent getting this page in the future is to use Privacy Pass.
Reduction of nitrobenzene with alkaline ascorbic acid: Kinetics and pathways. Recent developments in plasmon-assisted photocatalysis—A personal Perspective. Kinetics of the hydrogenation of a mixture of nitrobenzene and azoxybenzene on skeletal nickel in an aqueous solution of propan-2-ol. Find more information about Crossref citation counts. You may need to download version 2.0 now from the Chrome Web Store.
Oxidation of aniline into valuable products such as azoxybenzene, azobenzene, and nitrobenzene has been a great challenge due to the difficulty of controlling the selectivity of heterogeneous catalysts to form the desired products. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Reduction of carbon dioxide on photoexcited nanoparticles of VIII group metals, cnma201900182-sup-0001-misc_information.pdf.
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